In Canadain 2006, ethylene glycol was mainly used for anti-freeze mixtures and deicing fluids, and in the production of polyethylene terephthalate (PET) (Chinn 2007). Asia holds a prominent share in the global market production of MEG Some typical uses of Propylene Glycol include antifreeze and de-icing solutions and humectants. These include the following locations: Releases, disposal and recycling of ethylene glycol from airport operations for the years 1998 to 2005 are shown in Table 4. The amount of ethylene glycol used in other applications such as for oil and gas processing and in miscellaneous industrial applications, including its use as a solvent, totalled 70 kt in 2006 (Chinn 2007; CIS 2003). Other sources of untreated releases to land include chemical pulp mills, diamond mines and cement manufacturing. Toronto Pearson International: The Central Deicing Facility (CDF), built in 1998, was expanded in 1999-2000. Releases (untreated) to water have gone up significantly since 1994. The common name ethylene glycol literally means “the glycol derived from ethylene.” Since peaking in 1997 at 4698 tonnes, total untreated releases have trended downwards, reaching 2263 tonnes in 2005. ; 1,2-Ethandiol; Ucar 17; Dowtherm SR 1; Norkool, Click and drag to zoom, double click to reset zoom, Drag and Drop Attachments Here (optional), Comparison of Glycols Before and After 600 Water Injections on Rtx-Wax, Glycols on Rtx-BAC Plus 1 and 2 Column Set, Custom Residual Solvent Mix on Rxi-624Sil MS (using conditions from Pro, Column Comparison: Limit of Ethylene Glycol and Diethylene Glycol in Propylene Glycol. The SoS Report presents a detailed discussion of fate in the environment. The total annual capacity in 2006 from these three companies was 1540 kt: 370 kt for Alberta & Orient Glycol, 720 kt for the two MEGlobal Limited plants combined and 450 kt for Shell Chemicals (Chinn 2007). The hydroxyl groups on glycols undergo the usual alcohol chemistry, giving a wide variety of possible derivatives. Later symptoms may include a decreased level of consciousness, headache, and seizures. It is noteworthy that information indicates a trend in Canada towards substitution of ethylene glycol in paint formulations with other solvents/stabilizers (ICI Canada 2007). 1989; Howard 1990). Ethylene Glycol, Reagent is a colorless, odorless, sweet tasting organic compound that has a syrupy texture and is a liquid. Three additional deicing pads were built in 2004. Ethylene glycol, commonly referred to as EG, monoethylene glycol, or MEG, is the largest volume product of all ethylene glycols. m3/mol (Hine and Mookerjee 1975; Howard 1990). Ethylene glycol is a colorless, practically odorless, low-volatility, low-viscosity, hygroscopic liquid. {{item.Title_TH}} Thermo Scientific TraceGOLD TG-WaxMS GC column with 5m SafeGuard, a continuous 30m phased PET is manufactured into resins, fibres and films that are subsequently converted into numerous products such as bottles, packaging, and textiles (Chinn 2007). Sigma-Aldrich offers a number of Ethylene glycol products. NAMPA ID 83687. We will be in touch shortly. Canadaproduced 1410 kt and imported 3 kt of ethylene glycol from the United Statesin 2006. It is classified by the International Conference on Harmonisation of Technical Requirements for Registration of Pharmaceuticals for Human Use (ICH) as a Class 2 solvent or a solvent that is to be limited in pharmaceutical products (ICH 1997). It is completely miscible in water (Canada 1985; Budavari et al. In 2006, there were three companies (in four locations, all in Alberta) manufacturing ethylene glycol in Canada: Alberta & Orient Glycol (in Prentiss), MEGlobal Limited (in Fort Saskatchewan and Prentiss) and Shell Chemicals (in Scotford) (Chinn 2007). It is proposed to take no further action on ethylene glycol at this time under section 77 of the Act. Food Grade (1) GPC (1) Halal (3) HPLC (4) Hybridoma (3) Insect (1 ... gas chromatography (GC) (69) gel permeation chromatography (GPC) (16 ... as well as exogenous substrates including benzene, carbon tetrachloride, ethylene glycol, and nitrosamines which are premutagens found in cigarette smoke. It has many lab applications including use as an antifreeze, use as a desiccant, protecting group for carbonyls during chemical synthesis and as a preservative for biological specimens. This point is presented further in Appendix D. NPRI data show that land releases are the biggest component of total untreated releases in 2005. The concentration limit of 620 ppm of ethylene glycol in pharmaceutical products has been set by both the ICH and the United States Pharmacopoeia (ICH 1997; USPC 2007). For that year, scheduled air transportation and support activities for air transport account for 95% of untreated releases to land. 1,2-Ethanediol, Glycol, Ethylene Alcohol, Hypodicarbonous Acid, Monoethylene Glycol. Gas chromatography (GC) can also be used for analysis, but the ethylene glycol is difficult to detect and quantify due to its low molecular weight, low volatility and high polarity. While both air and land releases continue to show a downward trend, reported releases to water have increased fivefold since 2000. Cookies allow for a variety of features that make your visit to Restek more enjoyable. Long term outcomes may include kidney failure and brain damage. 1989). Introduction; 2. For the same period, the fraction of ethylene glycol that was released with no treatment compared with the total amount (including recycling and disposal) declined steadily from 53% in 1998 to 18% in 2005. Name: Ethylene Glycol – all grades Synonyms: 1,2-ethanediol, 1,2-dihydroxyethane, ethylene dehydrate CAS# 107-21-1 Product Uses: antifreeze in heat transfer fluids, humectant, plasticiser, hydraulic fluid, solvent Supplier Identifier: EMERGENCY INFORMATION Megaloid Laboratories Limited 5515 North Service Road, Suite 306 Stocked and ships daily from Atlanta, Georgia, Detroit, Michigan, and Salt Lake City, Utah. Ottawa Macdonald-Cartier International: A new biological treatment facility was opened in 2003. The amount of ethylene glycol used for the production of PET has increased since 2000 and was 69 kt (31% of the domestic demand) in 2006 (Chinn 2007). Sorry, your message could not be sent at this time. Total 2005 releases to water were reported as 572 tonnes, with oil and gas accounting for 446 tonnes (78%). 2006). Ethylene glycol poisoning is poisoning caused by drinking ethylene glycol. Ethylene glycol is available in four grades; hi purity, industrial and antifreeze grade. The exacting requirements of the polyester fibre market demand high purity MEG and a specific fibre-grade glycol is made for this purpose. The world MEG production capacity for the year 2016 was 34.8 million tons. Technical Grade Ethylene Glycol comes in 5 and 55 containers. 1219 INDUSTRIAL RD. GC Column Solvent Retention Table Technical Overview Introduction ... ethylene glycol monoethyl ether ethylene glycol monomethyl ether fluorobenzene Analyte DB-624 DB-1 DB-WAX. Grade: Laboratory: Density: 1.113g/cm³: Identification: Pass Test: Packaging: Glass Bottle: Vapor Pressure: 0.12mmHg at 20°C: Viscosity: 21 cP at 20°C: Decomposition Information >500°C: Boiling Point: 196°C: Color: Colorless: Melting Point-13°C: pH: 5.5 to 7.5: Quantity: 4L: Chemical Name or Material: Ethylene Glycol: Show More Show Less See a sample below or register for free to see much more. Iron and steel mills accounted for 44 tonnes (8%). Together these account for approximately 7% of the total releases to air (NPRI 2005). There was a peak of 422 tonnes injected underground in the 2000 reporting year. 5 3.24 3.72 14.63 15.32 11.93 8.65 15.60 9.15 21.69 26.63 13.14 5.82 18.10 4.27 14.75 8.60 12.19 17.68 5.66 analysis of diethylene glycol (DEG) and ethylene glycol (EG) according to the FDA method at levels of 0.5 mg/g in toothpaste. The term “disposal” indicates that the glycol received some form of treatment before being either released or sent to a municipal wastewater treatment system. Montréal-Trudeau: extensive improvements have been made since 2000, including a new enlarged deicing pad. Ethylene glycol chromatographic peak shape is often difficult to control and carryover can be a problem. Your message has been sent. Monoethylene glycol (MEG) accounts for more than 90% of the market for EG. The ethylene glycol used for anti-freeze mixtures and deicing fluids accounted for 70 kt (33% of the domestic demand) (Chinn 2007). Ethylene glycol, commonly referred to as EG, monoethylene glycol, or MEG, is the largest volume product of all ethylene glycols. This represents a decrease of 50%. 2. It can also be used in a variety of other products such as floor and wall adhesives, brake fluid, automotive wax/polish and floor wax/polish, in caulks and grout, concrete sealers and shoe polish. 1. Its reagent grade means this is the highest quality commercially available for this chemical and that … E691 Practice for Conducting an Interlaboratory Study to Determine the Precision of a Test Method. The amount of untreated ethylene glycol released to air has gone down since 1995 (Table 3). Where to buy Ethylene Glycol in the USA. E611 Test Methods for Low Concentrations of Diethlyene Glycol in Ethylene Glycol by Gas Chromatography. Please enable Javascript in your browser. All rights reserved. Phone (208) 375-7200 (800) 635-8930. For the same 1998 to 2005 period, untreated releases of ethylene glycol dropped from 2450 tonnes to 1232 tonnes. This amount has slowly decreased since 2000 with a slight increase from 2005 (Chinn 2007). This was due to an increase in the amount of ethylene glycol that was either recycled or disposed of. Aeration to Truro Creek, one of two receiving water bodies for airport runoff, was started in 2001. พันธกิจ {{mission.Subject_TH}} {{mission.Title_TH}} ผลิตภัณฑ์ของเรา. Ethylene Glycol (Final Content) Ethylene Glycol (Final Content) Table of Contents Synopsis; List of Tables; List of Figures; List of Acronyms and Abbreviations; 1. Ethylene Glycol, technical grade, Boise Idaho. Summary of Information Critical to the Risk Assessment Under CEPA 1999; 3. DEG. Order directly online and save. Ethylene glycol, also called ethane-1,2-diol, the simplest member of the glycol family of organic compounds. Half-lives are estimated to typically range from 0.35 to 3.5 days in air, 2 to 12 days in water, 4 to 24 days in groundwater and 2 to 12 days in soil, but may exceed these ranges, depending on environmental conditions. Ethylene glycol United States Pharmacopeia (USP) Reference Standard; CAS Number: 107-21-1; Synonym: Ethylene glycol, 1,2-Ethanediol; Linear Formula: C2H6O2; find USP-1265515 MSDS, related peer-reviewed papers, technical documents, similar products & more at Sigma-Aldrich. Winnipeg James Armstrong Richardson International: A central deicing facility was opened in 2005. Subscribers to our Commodity Price Database have access to Ethylene Glycol and as many as 217 other commodities prices across several countries from main world regions. Toxicity and death may occur after drinking even a small amount. As can be seen, there is an increase in the total for these three categories from 4577 tonnes in 1998 to 6745 tonnes in 2005. Thus, untreated releases have declined in this period, both numerically and proportionally. This site requires that Javascript be enabled. 1989). By using this website, you agree to the use of cookies in accordance with our guidelines. USP grade is used in the production of pharmaceuticals, food colors and flavors, foods, cosmetics, tobacco, fragrances, personal care products, and animal feed. Annual volumes of untreated releases from all reporting sources of ethylene glycol to air, water and land for the period 1994 to 2005 are shown in Table 3. A glycol is an alcohol with two hydroxyl groups on adjacent carbon atoms (a 1,2-diol). Once released into the environment, ethylene glycol partitions mainly into surface water or groundwater. There are year-to-year fluctuations, but the total of releases, disposal and transfers for recycling (together taken as an indirect measure of usage) generally increased while untreated releases dropped. The octanol/water partition coefficient of ethylene glycol is very low (i.e., log Kow = -1.36) (Verschueren 1983; Budavari et al. In total, 1200 kt of ethylene glycol were exported in the same year, mainly to China(Chinn 2007). As indicated in the SoS Report, ethylene glycol is used in large volumes for aircraft deicing/anti-icing practices and these volumes are reportedly released to land (see below); however, airport collection facilities and drainage systems may divert substantial quantities to the aquatic environment. Summary of Information Critical to the Risk Assessment Under CEPA 1999, Appendix B: Literature Search Strategy -- New Information for the Human Health Assessment, Appendix C: Literature Search Strategy -- New Information for the Ecological Assessment, Appendix D: Management of Ethylene Glycol at Canadian Airports, Canadian Environmental Protection Act (CEPA) Environmental Registry, 2.1 Identity and Physical/Chemical Properties, Ministerial and Governor-in-Council appointments. Column Comparison: Limit of Ethylene Glycol and Diethylene Glycol in Propylene Glycol Column Comparison: Limit of Ethylene Glycol and Diethylene Glycol in Propylene Glycol ... Agilent/HP6890 GC: Notes: Columns tested: Rxi-624Sil MS, ZB-624, and DB-624: Download PDF RELATED CHROMATOGRAM LIBRARY SEARCHES. Early symptoms include intoxication, vomiting and abdominal pain. Ethylene Glycol. Ethylene glycol is available in four grades; polyester, hi … A sharp increase in releases occurred in 2003 and continued increases were reported up to 2005. The worldwide production capacity of ethylene glycol in 2006 was approximately 19 500 kilotonnes (kt), where the majority went into the production of polyethylene terephthalate (81.5%) (Chinn 2007). 1993).It has a sweet taste and imparts a warming sensation to the tongue when swallowed (Beasley and Buck 1980). The quantities used in Canadafor most of these products are unknown. It is miscible with water und polar organic solvents such as ethanol and acetone. E1064 Test Method for Water in Organic Liquids by Coulometric Karl Fischer Titration. Go. Sample Ethylene glycol, diethylene glycol, triethylene glycol Injection method Split (1:200) Injection volume 1.0 µL GC Column DB-5 ms, ID 0.25 mm × Length 30 m, film thickness 0.25 µm Oven program 80℃(2 min)→ 20℃/min → 280℃(2 min) Results Analytical results are shown below. 1,2-Ethanediol; Ethylene glycol; Ethylene alcohol; Glycol; Glycol alcohol; Lutrol 9; Macrogol 400 BPC; Monoethylene glycol; Ramp; Tescol; 1,2-Dihydroxyethane; 2-Hydroxyethanol; HOCH2CH2OH; Dihydroxyethane; Ethanediol; Ethylene gycol; Glygen; Athylenglykol; Ethane-1,2-diol; Fridex; M.e.g. Sort By: Price: Low to High Price: High to Low Most Popular Title Manufacturer Newest Oldest Availability. 2 Determination of Ethylene Glycol and Diethylene Glycol in a Sorbitol Solution Vial Kit, 1.5 mL glass sample vials, with caps and slit septa (vial kit, P/N 055427) Vacuum pump PEEK™ Tubing: Black (0.25 mm or 0.01 in i.d., P/N 052307 for 5 ft) tubing used for liquid line connections from the pumps to the injection valve. It is mainly used for two purposes, as a raw material in the manufacture of polyester fibers and for antifreeze formulations. We have compiled a list of Ethylene Glycol Products in America. DEG is used in the manufacture of unsaturated polyester resins, polyurethanes and plasticisers. It is an odorless, colorless, sweet-tasting, viscous liquid. Releases then were reported at 91 tonnes, mostly from the paper products and the primary steel industry sectors. FAX (208) 376-3605 For more information, see our privacy policy. In 1995, their production volumes ranked them among the top twenty organic chemicals in the United States. Ethylene glycol (IUPAC name: ethane-1,2-diol) is an organic compound with the formula (CH2OH)2. The physical and chemical properties of ethylene glycol, also known as monoethylene glycol and 1,2-ethanediol, are presented in Table 1.Ethylene glycol is a clear, colourless, odourless, relatively non-volatile, viscous liquid (Nielsen et al. Propylene Glycol is a non-toxic alternative to ethylene glycol and is often used in foods and pharmaceuticals. Ethylene oxide (EO) and ethylene glycol (EG) are widely used industrial organic intermediates. The paper products sector, including pulp mills, reported a significant drop. Ethylene glycol is used as a formulant in pesticide products in Canada(e-mail from Pest Management Regulatory Agency [PMRA] to Healthy Environments and Consumer Safety [HECS] September 2009, unreferenced). Intratec provides Ethylene Glycol pricing data, covering 13 years of historical prices and forecasts. Table 3 shows that compared with 1994, when underground injections (mostly on-site) amounted to 77 tonnes, some 93 tonnes were disposed of in this manner in the 2005 reporting year. The global production was dominated by Asian countries which accounted for 15.1 million tons from the total production. The addition of glycol antifreeze (such as Dowfrost HD™ propylene glycol, Dowfrost™ food grade propylene glycol or Dowtherm SR-1™ ethylene glycol) to water in hydronic heating and cooling systems, lowers the freezing point of your heat transfer fluid mixture. Ethylene glycol is a major component of deicing solutions used in a variety of transportation applications, including cars, boats and aircraft, as well as on airport runways during the cold winter months. Please try again later, or contact Restek or your local Restek representative via phone. Since 2000, several major federal airports have built and/or improved their glycol handling facilities. The natural gas industry in western Canadais the biggest user of this type of disposal method (NPRI 2005). Two approaches have been used to determine DEG and EG in toothpaste at a low level of 0.1 mg/mL in a full scan mode. An on-site glycol recycling facility was commissioned in 2005 (GTAA 2005). While this sector was previously reported as the biggest contributor of releases to water, it accounted for only 8 tonnes (1.4%) in 2005. 1. Table 2 presents data from the National Pollutant Release Inventory (NPRI) on total industrial annual volumes of releases, disposal and recycling of ethylene glycol from all reporting sources from 1994 to 2005. It is very hygroscopic and will absorb up to 200% of its weight in water at 100% relative humidity (Budavari et al. View information & documentation regarding Ethylene glycol, including CAS, MSDS & more. Risk Assessment under CEPA 1999 Other contributing industrial activity includes motor vehicle brake and motor manufacturing, printing, and iron ore mining. Ethylene glycol Reagent Grade, ≥99%, CAS Number: 107-21-1,(102466 Honeywell).Shop now or request a quote. Ethylene glycol: Glycols Standard: European Pharmacopoeia/ICH Class 2 Mix C: Residual Solvents Class 2 - Mix C: Glycerin Standard Mix: Propylene Glycol Standard Mix: Sorbitol Standard Mix It does not bioaccumulate or persist in the environment, primarily due to biodegradation. Background "Notice of Suspension of five-year period" and State of the Science Other applications are served by an industrial grade. While petrochemical manufacture is still the biggest contributor (144 tonnes, or 49%), significant amounts are also released by conventional oil and gas extraction (85 tonnes, or 29%), as well as from the paint and coating industry (20 tonnes, or 7%), resin and synthetic rubber manufacturing (11 tonnes, or 4%), and petroleum refineries (10 tonnes, or 3.5%) (NPRI 2005). Ethylene glycol may also be present in pharmaceutical products as a residual solvent. You may also obtain copies of the final screening assessment report by contacting existing.substances.existantes@ec.gc.ca. Restek Corporation, U.S., 110 Benner Circle, Bellefonte, PA 16823Copyright © 2020 Restek Corporation. Mono-Ethylene Glycol Production Capacity by Region. In addition, ethylene glycol may be used in asphalt emulsion paints; as a coolant and heat transfer fluid; in low-pressure laminates; in glycol diacetate production; in low-freezing dynamite; as a solvent mixture for cellulose esters and ether (a softening agent in cellophane in particular), printing inks, stamp pad inks, ballpoint pen inks, and wood stains; in lacquers; in alkyd resins; in leather dyeing; in textile processing; in humectants; and as a foam stabilizer (ATSDR 2007; Lewis 2007; O’Neil et al. It is completely miscible with water and many organic liquids. Ethylene glycol is a clear, viscous liquid with a sweetish taste (molar mass 62.07 g/mol, boiling point 197 °C, melting point −16 °C, vapour pressure 5.3 Pa at 20 °C). Ethylene glycol has been found to biodegrade rapidly in the aquatic environment and therefore has the potential to induce depletion of the dissolved oxygen (DO) in receiving waters. This substance can also be used in a variety of other products such as in automotive anti-freeze/coolant and wax/polish; brake fluid; as a solvent in adhesives; in floor wax/polish; in caulks and grout, spackling compound, concrete sealers, and shoe polish (NLM 2009; Chinn 2007; US EPA 1986). Vancouver International: work began on a new deicing pad in 2005 and the pad was operational in 2006. Edmonton International: A subsurface-flow (SSF) wetland facility was commissioned in 2000–2001 to treat ethylene glycol-containing aircraft deicing/anti-icing fluids (. If looking for a particular Ethylene Glycol to purchase, simply use the search box, then use the suppliers website link for more information or prices. Ethylene glycol is present in various surface coatings, including latex paint, as a slow-evaporating solvent and/or freeze-thaw stabilizer, as well as to provide coalescence and wet-edge control (Chinn 2007; US EPA 1986; NLM 2009). Use of consumer products containing ethylene glycol may also contribute to releases to air. Ethylene glycol is a key ingredient in automotive antifreeze and coolant, to help keep a car’s engine from overheating and from freezing in the winter. ethylene, Activities for air transport account for approximately 7 % of untreated ethylene glycol ethylene glycol gc grade in and! Significant drop alcohol chemistry, giving a wide variety of features that make your visit to Restek more enjoyable untreated... Sweet taste and imparts a warming sensation to the use of consumer products containing ethylene dropped. With water and many organic liquids by Coulometric Karl Fischer Titration usual alcohol chemistry, giving a wide variety possible. 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